Publikationen seit 2017

2018

Twofold Oxidized and Twofold Protonated Redox-Active Guanidine: An Ultimate Intermediate in Proton-Coupled Electron-Transfer Reactions

Catalyst-Free Hydroboration of CO₂ with a Nucleophilic Diborane(4)

Di- and Tetranuclear Transition Metal Complexes of a Tetrakisguanidino-Substituted Phenazine Dye by Stepwise Coordiation

Boron(II) Cations: Interplay between Lewis-Pair Acceptor and Electron Donor Properties

Intramolecular Metal-Ligand Electron Transfer Triggered by Co-Ligand Substitution

Solvent Control of Ligand-Metal Electron Transfer in Mononuclear Copper Complexes with Redox-Active Bisguanidine Ligands

Efficient n-Doping and Hole-blocking in Single-Walled Carbon Nanotube Transistors with 1,2,4,5-Tetrakis(tetramethyl-guanidino)benzene

Guanidines as Reagents in Proton-Coupled Electron Transfer Reactions and Redox Catalysts

Metal Cluster Models for Heterogeneous Catalysis: A Matrix-Isolation Perspective

Nucleophilic Neutral Diborane(4) Compounds with sp³-sp³-Hybridized Boron Atoms

Tuning the Nucleophilicity of Electron-Rich diborane(4) Compounds with Bridging Guanidinate Substituents by Substitution

On the Dual Reactivity of a Nucleophilic Dihydrido-Diborane: Reaction at the B-B Bond and/or the B-H Bond  

Valence Tautomerism in Copper Coordination Chemistry

The Vibrations of V204: Matrix Isolation and Quantum Chemical Calculations

Oxidation of Organic Molecules with a Redox-Active Guanidine Catalyst

Incorporation of a Redox-Active Bisguanidine in Low-Dimensional Tin- and Lead-Iodide Structures

Inter- and Intramolecular Electron Transfer in Copper Complexes: Electronic Entatic State with Redox-Active Guanidine Ligands

O. Hübner, H.-J. Himmel*, Angew. Chem. 2017, 129, 12510-12514; Angew. Chem. Int. Ed. 2017, 56, 12340-12343

Hot Paper

Multiple Metal-Metal bond or No Bond? The Electronic Structure of V₂O₂

Metal-Free Nitrile Diboration through Activation by an Electron-Rich Diborane

Homo- and Heterobinulear Cu and Pd Complexes with a Bridging Redox-Active Bisguanidino-Substituted Dioxolene Ligand: Electronic Structure and Metal-Ligand Electron Tansfer

Hydrogen-Atom Transfer (HAT) Initiated by Intramolecular Ligand-Metal Electron Transfer

aRMSD: A Comprehensive Tool for Strucural Analysis

B. Eberle, E. Kaifer, H.-J. Himmel*, Angew. Chem. 2017, 129, 3408-3412; Angew. Chem. Int. Ed. 2017, 56, 3360-3363

A Stable Hexakis(guanidino)benzene: Realization of the Strongest Neutral Organic Four-Electron Donor